Unexpected Steric Effects of “Remote” Alkyl Groups on the Rate of Conjugate Additions to Alkyl α,β-Ethylenic Sulfones, Sulfoxides, and Esters
Author:
Affiliation:
1. Department of Chemistry, School of Arts and Sciences, The Johns Hopkins University, Baltimore, Maryland 21218
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo062155g
Reference20 articles.
1. Part B: Reactions and Synthesis
2. Perlmutter, P.Conjugate Addition Reactions in Organic Synthesis; Pergamon Press: New York, 1992; p 106.
3. Acyclic stereoselection. 47. Stereochemistry of the Michael addition of ester and ketone enolates to .alpha.,.beta.-unsaturated ketones
4. Radical addition to amide-substituted alkenes: stereoselective intermolecular radical additions
5. Inositols as chiral templates: 1,4-conjugate addition to tethered cinnamic esters
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