TEMPO-Mediated Catalysis of the Sterically Hindered Hydrogen Atom Transfer Reaction between (C5Ph5)Cr(CO)3H and a Trityl Radical-Reference-Cited by-同舟云学术

TEMPO-Mediated Catalysis of the Sterically Hindered Hydrogen Atom Transfer Reaction between (C5Ph5)Cr(CO)3H and a Trityl Radical

Published:2019-01-22 Issue:5 Volume:141 Page:1882-1886
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Gunasekara Thilina¹^ORCID,Abramo Graham P.¹,Hansen Andreas²^ORCID,Neugebauer Hagen²,Bursch Markus²,Grimme Stefan²^ORCID,Norton Jack R.¹^ORCID

Affiliation:

1. Department of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027, United States

2. Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms Universität Bonn, Beringstraße 4, 53115 Bonn, Germany

Funder

Basic Energy Sciences

Deutsche Forschungsgemeinschaft

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.8b12892

Reference46 articles.

1. Relative rates of hydrogen atom (H.cntdot.) transfer from transition-metal hydrides to trityl radicals

2. A direct comparison of the rates of degenerate transfer of electrons, protons, and hydrogen atoms between metal complexes

3. Intrinsic barriers to atom transfer (abstraction) processes; self-exchange rates for Cp(CO)3M.bul. radical/Cp(CO)3M-X halogen couples

4. Calorimetric and equilibrium studies on some stable nitroxide and iminoxy radicals. Approximate oxygen-hydrogen bond dissociation energies in hydroxylamines and oximes

5. Homolytic bond dissociation energies of the benzylic carbon-hydrogen bonds in radical anions and radical cations derived from fluorenes, triphenylmethanes, and related compounds

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