Changes in Regioselectivity of H Atom Abstraction during the Hydroxylation and Cyclization Reactions Catalyzed by Hyoscyamine 6β-Hydroxylase
Author:
Affiliation:
1. Department of Chemistry, University of Texas at Austin, Austin, TX 78712, United States
2. Division of Chemical Biology and Medicinal Chemistry, College of Pharmacy, University of Texas at Austin, Austin, TX 78712, United States
Funder
Welch Foundation
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.8b11585
Reference35 articles.
1. Hausinger, R. P. In 2-Oxoglutarate-dependent oxygenases; Schofield, C. J., Hausinger, R. P., Eds. The Royal Society of Chemistry: Cambridge, U.K., 2015; pp 1–58.
2. Versatility of biological non-heme Fe(II) centers in oxygen activation reactions
3. Non-Heme Fe(IV)–Oxo Intermediates
4. Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates
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