TEMPO/NaIO4−SiO2: A Catalytic Oxidative Rearrangement of Tertiary Allylic Alcohols to β-Substituted α,β-Unsaturated Ketones
Author:
Affiliation:
1. Graduate School of Pharmaceutical Sciences, Tohoku University, Aobayama 6-3, Sendai 980-8578, Japan
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol801673r
Reference51 articles.
1. A Facile Method for the Bishomologation of Ketones to α,β-Unsaturated Aldehydes: Application to the Synthesis of the Cyclohexanoid Components of the Boll Weevil Sex Attractant
2. Direct oxidation of tertiary allylic alcohols. A simple and effective method for alkylative carbonyl transposition
3. Oxidative rearrangements of tertiary and some secondary allylic alcohols with chromium(VI) reagents. A new method for 1,3-functional group transposition and forming mixed aldol products
4. Enantioconvergent route to α-cuparenone from dicyclopentadiene
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