EPR Spin-Trapping Evidence for the Direct, One-Electron Reduction of tert-Butylhydroperoxide to the tert-Butoxyl Radical by Copper(II): Paradigm for a Previously Overlooked Reaction in the Initiation of Lipid Peroxidation
Author:
Affiliation:
1. Contribution from the Gray Cancer Institute, P.O. Box 100, Mount Vernon Hospital, Northwood, Middlesex, HA6 2JR, United Kingdom
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja034416z
Reference41 articles.
1. The role of lipid peroxidation and antioxidants in oxidative modification of LDL
2. Copper-induced lipid peroxidation in liposomes, micelles, and LDL: Which is the role of vitamin E?
3. Simulation of the Induction of Oxidation of Low-Density Lipoprotein by High Copper Concentrations: Evidence for a Nonconstant Rate of Initiation
4. A Critical Overview of the Chemistry of Copper-Dependent Low Density Lipoprotein Oxidation: Roles of Lipid Hydroperoxides, α-Tocopherol, Thiols, and Ceruloplasmin
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