Synthesis of Ortho-Palladated Phenol Derivatives. Study of Their Reactivity with Carbon Monoxide and Isonitriles

Author:

Vicente José1,Abad José-Antonio1,Förtsch Walter1,Jones Peter G.2,Fischer Axel K.3

Affiliation:

1. Grupo de Química Organometálica, Departamento de Química Inorgánica, Facultad de Química, Universidad de Murcia, Aptdo. 4021, E-30071 Murcia, Spain

2. Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, 38023 Braunschweig, Germany

3. Institut für Chemie, Universität Magdeburg, Universitätsplatz 2, 37106 Magdeburg, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference106 articles.

1. Synthesis of Palladium Complexes with ortho-Functionalized Aryl Ligands

2. Synthesis and Reactivity of 2-Aminophenylpalladium(II) Complexes: Insertion Reactions of Oxygen and Carbon Monoxide into Carbon−Palladium Bonds—New Examples of “Transphobia”

3. Synthesis of Mercury(II) and Palladium(II) Organometallic Derivatives of Terephthaldehyde by Metalation, Transmetalation, Oxidation, and Condensation Reactions. X-ray Crystal Structures of trans-[PdCl{C6H3(CO2H)2-2,5}(PPh3)2]·Me2CO·2MeOH, trans-[PdCl{C6H3(CHO)-2-(CO2H)-5}(PPh3)2]·2CH2Cl2, and [Pd{C6H3(CHNC6H4NH2-4)-2-(CHO)-5}(N,N,N‘,N‘-Tetramethylethylenediamine)]CF3SO3. Molecular Assemblies through [Pd]−Cl···HO2C−Aryl and [Pd]−Cl···HOMe  HO(O)C−Aryl Hydrogen Bonds

4. Palladium-Assisted Formation of Carbon−Carbon Bonds. 7.1 Reactions of (2,3,4-Trimethoxy-6-X-phenyl)palladium Complexes with Alkynes (X = C(O)NHBut) and Isocyanides (X = C(O)NHBut, C(O)Me, CHO):  Crystal and Molecular Structures of [Pd{C6H{C(O)NHBut}-6-(OMe)3-2,3,4}(bpy)](CF3SO3), [Pd{C(CO2Me)C(CO2Me)C6H{C(O)NHBut}-6-(OMe)3-2,3,4)}- Cl(PPh3)], [Pd{C(NXy)C6H{C(O)NHBut}-6-(OMe)3-2,3,4}- (bpy)](CF3SO3), and the Ketenimine 2-(2,6-Dimethylphenyl)-1-(((2,6-dimethylphenyl)imino)- methylene)-5,6,7-trimethoxy-3-oxoisoindoline

5. Room-temperature oxidation of 2-aminobenzoyl- to 2-aminobenzoato-palladium(ii) complexes and of coordinated PPh3 by atmospheric oxygen; X-ray crystal structure of [(PPh3)2Pd(NH2C6H 4CO2-2)Pd{C(O)C6H 4NH2-2}(PPh3)]O3 SCF3

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