Reversed Stereochemical Control in the Presence of CeCl3 and TiCl4 in the Lewis Acid Mediated Reduction of α-Alkyl-β-keto Esters by Metal Hydrides. A General Methodology for the Diastereoselective Synthesis of syn- and anti-α-Alkyl-β-hydroxy Esters
Author:
Affiliation:
1. Dipartimento di Chimica, Università della Calabria, I-87030 Arcavacata di Rende, Cosenza, Italy
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo9821574
Reference65 articles.
1. An introduction of chiral centers into acyclic systems based on stereoselective ketone reduction
2. Unusual anti-Selective Reduction of α-Methyl β-Alkylketo Esters by Organotin Hydride-Titanium Tetrachloride
3. Stereoselective reduction of 2-methyl-3-oxo esters (or amides) with sodium borohydride catalyzed by manganese(II) chloride or tetrabutylammonium borohydride. A practical preparation of erythro and threo-3-hydroxy-2-methyl esters (or amides)
4. Fluoride ion-catalyzed reduction of aldehydes and ketones with hydrosilanes. Synthetic and mechanistic aspects and an application to the threo-directed reduction of .alpha.-substituted alkanones
Cited by 68 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Triborane (B3H7)-mediated regioselective substitution reactions of pyridine derivatives;Chemical Science;2024
2. Deracemization of diastereomerically pure syn- and anti-α-substituted β-hydroxyesters by Novozyme 435 lipase and determination of their absolute configuration by NMR spectroscopy;Molecular Catalysis;2021-06
3. Cerium(III) Chloride;Encyclopedia of Reagents for Organic Synthesis;2021-04-30
4. Diastereoselective Reduction of Selected α-substituted β-keto Esters and the Assignment of the Relative Configuration by 1H-NMR Spectroscopy;Current Organocatalysis;2020-12-07
5. The effects of cerium ions on the curing, polymerisation and condensation of hybrid sol-gel coatings;Journal of Non-Crystalline Solids;2019-04
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3