N,N‘-Diisopropyl-N‘ ‘-bis(trimethylsilyl)guanidinate Ligand as a Supporting Coordination Environment in Yttrium Chemistry. Synthesis, Structure, and Properties of Complexes [(Me3Si)2NC(Ni-Pr)2]YCl2(THF)2, [(Me3Si)2NC(Ni-Pr)2]Y(CH2SiMe3)2(THF)2, and [(Me3Si)2NC(Ni-Pr)2]Y[(μ-H)(μ-Et)2BEt]2(THF)
Author:
Affiliation:
1. G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, Tropinia 49, 603600 Nizhny Novgorod GSP-445, Russia
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic701215t
Reference59 articles.
1. The coordination chemistry of guanidines and guanidinates
2. Bis(trimethylsilyl)benzamidinate: a promising spectator ligand in organoyttrium chemistry. Synthesis and reactivity of {[C6H5C(NSiMe3)2]2Y-.mu.-R}2 (R = H, C.tplbond.CH) and x-ray structure of {[C6H5C(NSiMe3)2]2Y-.mu.-C.tplbond.CH}2
3. Preparation of Scandium Complexes with Benzamidinate Ligands: Synthesis and Reactivity of Alkyl and Hydrido Derivatives
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