Unexpected P−Si or P−C Bond Cleavage in the Reaction of Li2[(C5Me4)SiMe2PR] (R = Cyclohexyl, 2,4,6-Me3C6H2) and Li[(C5H4)CMe2PHR] (R = Ph, tBu) with ZrCl4 or [TiCl3(thf)3]: Formation and Molecular Structure of the ansa-Metallocenes [{(η-C5Me4)2SiMe2}ZrCl2] and [{(η-C5H4)2CMe2}MCl2] (M = Ti, Zr)
Author:
Affiliation:
1. Institut für Anorganische Chemie der Universität, D-04103 Leipzig, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om990763z
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1. Das Mülheimer Normaldruck-Polyäthylen-Verfahren
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3. Crystal structure and propene polymerization characteristics of bridged zirconocene catalysts
4. C2-symmetric ansa metallocenes of titanium and zirconium with a ligand system that yields pure rac isomer: preparation and crystal structures of rac-η5-C5H22-SiMe34-CMe3)2SiMe3MCl2(M = Ti or Zr)
5. Polymerisation von Propen und Buten mit einem chiralen Zirconocen und Methylaluminoxan als Cokatalysator
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