Chemistry of η2-CS2 Niobocene Complexes: Synthesis and Characterization of New 1,3-Dithiol-2-ylidene Complexes via Reactions with Activated Alkynes-Reference-Cited by-同舟云学术

Chemistry of η2-CS2 Niobocene Complexes: Synthesis and Characterization of New 1,3-Dithiol-2-ylidene Complexes via Reactions with Activated Alkynes

Published:1996-04-16 Issue:8 Volume:15 Page:1966-1971
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Antiñolo Antonio¹,del Hierro Isabel¹,Fajardo Mariano¹,Garcia-Yuste Santiago¹,Otero Antonio¹,Blacque Olivier¹,Kubicki Marek M.¹,Amaudrut Jacques¹

Affiliation:

1. Departamento de Química Inorgánica Orgánica y Bioquímica, Facultad de Químicas, Campus Universitario, Universidad de Castilla-La Mancha, 13071-Ciudad Real, Spain, Departamento de Química Inorgánica, Campus Universitario, Universidad de Alcalá, 28871-Alcalá de Henares, Spain, Laboratoire de Synthèse et d'Electrosynthèse Organométalliques, CNRS URA 1685, Faculté des Sciences Gabriel, 6, Bd. Gabriel, 21000 Dijon, France, and Laboratoire des Organométalliques, Faculté des Sciences et des Techniques, 25030...

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om950916s

Reference17 articles.

1. Bianchini, C.; Mealli, C.; Meli, A.; Sabat, M. InStereochemistry of Organometallic and Inorganic Compounds; Bernal, I., Ed.; Elsevier: Amsterdam, 1986; Vol. 1, pp 146−254.

2. Novel route to iron-carbene derivatives via addition of alkynes to carbon disulfide-iron complexes. Rearrangement of (1,3-dithiol-2-ylidene)iron complexes into heterometallacycles

3. Studies of the reactivity towards insertion and electrophilic processes of Nb-H and Nb(η2-CS2) moieties of bis(trimethylsilylcyclopentadienyl)niobium complexes

4. Easy route for the synthesis of iminoacyl niobocene complexes. The first x-ray structure of an (.eta.2-iminoacyl)niobium complex, {Nb(.eta.5-C5H4SiMe3)2Cl(.eta.2(C,N)-EtPhHCCNPh}+BF4-

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