Iodination of α-Phosphino Enolate Complexes of Palladium(II) and Platinum(II). Synthesis and Crystal Structures of [(dmba)Pd{Ph2PC(I) C( O)Ph}] and of the Dipalladium(II) Complex [(dmba)Pd{Ph2PC C( O)Ph}Pd(I)(tmeda)] Obtained by Palladium(0) Insertion into the Carbon−Iodine Bond-Reference-Cited by-同舟云学术

Iodination of α-Phosphino Enolate Complexes of Palladium(II) and Platinum(II). Synthesis and Crystal Structures of [(dmba)Pd{Ph2PC(I) C( O)Ph}] and of the Dipalladium(II) Complex [(dmba)Pd{Ph2PC C( O)Ph}Pd(I)(tmeda)] Obtained by Palladium(0) Insertion into the Carbon−Iodine Bond

Published:1996-01-01 Issue:24 Volume:35 Page:7174-7180
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Andrieu Jacques¹,Braunstein Pierre¹,Dusausoy Yves¹,Ghermani Nour Edine¹

Affiliation:

1. Laboratoire de Chimie de Coordination, Associé au CNRS (URA 416), Université Louis Pasteur, 4 rue Blaise Pascal, F-67070 Strasbourg Cédex, France, and Laboratoire de Cristallographie et Modélisation des Matériaux Minéraux et Biologiques, Associé au CNRS (URA 809), Université Henri Poincaré Nancy 1, B.P. 239, F-54506 Vandoeuvre-les-Nancy Cédex, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic951507r

Reference46 articles.

1. Reaction of α-phosphino functional carbanions with co-ordinated nitriles. Synthesis of bis-chelate (P,N) platinum complexes; X-ray crystal and molecular structure of trans-Pt[P(Ph)2C(CO2Et)C(Ph)NH]2

2. Complexes of functional phosphines. 4. Coordination properties of (diphenylphosphino)acetonitrile, ethyl (diphenylphosphino)acetate and corresponding carbanions. Characterization of a new facile reversible carbon dioxide insertion into palladium(II) complexes

3. Complexes of functional phosphines. 6. Five-membered palladium or platinum metallacycles resulting from nucleophilic attack of .alpha.-phosphino carbanions on organonitriles. Synthesis and crystal structure of [cyclo] trans-Pt[Ph2PC(COOC2H5)C(Ph)NH]2 and [cyclo] Pd(C-N)Cl[.mu.-Ph2PCH2C(NH)C(CN)PPh2]Pd(C-N) [(C-N) = (o-C6H4CH2N(CH3)2)]

4. Reactions of carbon dioxide with carbon-carbon bond formation catalyzed by transition-metal complexes

5. Complexes of functional phosphines

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