Palladium-Catalyzed trans- and cis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents:  Ligand-Dependent Complementary Stereoselectivity

Author:

Daini Masaki1,Yamamoto Akihiko1,Suginome Michinori1

Affiliation:

1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference18 articles.

1. Boronic Acids

2. Catalytic Hydroboration with Rhodium Complexes

3. Formation of Aryl- and Benzylboronate Esters by Rhodium-Catalyzed C−H Bond Functionalization with Pinacolborane

4. Reviews on the catalytic boron-element addition:  (a) Beletskaya, I.; Moberg, C.Chem. Rev.2006,106, 2320. (b) Suginome, M.; Matsuda, T.; Ohmura, T.; Seki, A.; Murakami, M. InComprehensive OrganometallicChemistry III; Crabtree, R.; Mingos, M., Eds., Ojima, I., Vol. Ed.; Elsevier,2007; Vol. 10, p 725.

5. Palladium(0)-catalyzed thioboration of terminal alkynes with 9-(alkylthio)-9-borabicyclo[3.3.1]nonane derivatives: stereoselective synthesis of vinyl sulfides via the thioboration-cross-coupling sequence

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