Intramolecular [1 + 2] and [3 + 2] Cycloaddition Reactions of Cyclopropenone Ketals
Author:
Affiliation:
1. Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja103933n
Reference21 articles.
1. Thermal reactions of cyclopropenone ketals. Key mechanistic features and scope of the cycloaddition reactions of delocalized singlet vinylcarbenes: three-carbon 1,1-/1,3-dipoles
2. Effective, thermal one-carbon + two-carbon cycloaddition of cyclopropenone ketals with electron-deficient olefins: Cyclopropane formation.
3. Regioselective Generation and Stereoselective [1 + 2] Cycloaddition of Substituted Vinylcarbenes
4. An effective, thermal three-carbon + two-carbon cycloaddition for cyclopentenone formation: formal 1,3-dipolar cycloaddition of cyclopropenone ketals
5. Thermal, three-carbon + two-atom cycloaddition of cyclopropenone ketals with carbon-heteroatom double bonds: Butenolide, furan, and γ-keto ester preparation.
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