Alkylidene-Centered Rearrangement of a Tantalum Alkylidene Alkoxide Species with the N,C,N-Bis-ortho-chelated 1,2,6-Trisubstituted Aryldiamine Ligand [C6H3(CH2NMe2)2-2,6]- to a Product with a C,N-Mono-ortho-chelated 1,2,4-Trisubstituted Aryldiamine Ligand. X-ray Molecular Structure of [TaCl(CH-t-Bu){C6H3(CH2NMe2)2-2,4}(O-t-Bu)]-Reference-Cited by-同舟云学术

Alkylidene-Centered Rearrangement of a Tantalum Alkylidene Alkoxide Species with the N,C,N-Bis-ortho-chelated 1,2,6-Trisubstituted Aryldiamine Ligand [C6H3(CH2NMe2)2-2,6]- to a Product with a C,N-Mono-ortho-chelated 1,2,4-Trisubstituted Aryldiamine Ligand. X-ray Molecular Structure of [TaCl(CH-t-Bu){C6H3(CH2NMe2)2-2,4}(O-t-Bu)]

Published:1997-09-01 Issue:20 Volume:16 Page:4260-4267
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Rietveld Marco H. P.¹,Klumpers Elzebé G.¹,Jastrzebski Johann T. B. H.¹,Grove David M.¹,Veldman Nora¹,Spek Anthony L.¹,van Koten Gerard¹

Affiliation:

1. Debye Institute, Department of Metal-Mediated Synthesis, and Bijvoet Center for Biomolecular Research, Department of Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om960907z

Reference32 articles.

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4. Synthesis of Novel Mono(pentamethylcyclopentadienyl)tantalacycloalkyl and -tantalacycloalkylidene Complexes. Crystal Structure of [TaCp*Cl2{η3-C6H4(2-CH2NMeCH2)}]

5. .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds

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