Rationale for the Acidity of Meldrum's Acid. Consistent Relation of C−H Acidities to the Properties of Localized Reactive Orbital
Author:
Affiliation:
1. Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo049456f
Reference24 articles.
1. Ion pairing and reactivity of enolate anions. 5. Thermodynamics of ionization of .beta.-di- and tricarbonyl compounds in dimethyl sulfoxide solution and ion pairing of their alkali salts
2. Acidity of (Z)- and (E)-methyl acetates: relationship to Meldrum's acid
3. Benzyne, cyclohexyne, and 3-azacyclohexyne and the problem of cycloalkyne versus cycloalkylideneketene genesis
4. New Insight on the Origin of the Unusual Acidity of Meldrum's Acid from ab Initio and Combined QM/MM Simulation Study
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