Dynamic Theory of Liquid Junction Potentials-Reference-Cited by-同舟云学术

Dynamic Theory of Liquid Junction Potentials

Published:2009-12-10 Issue:1 Volume:114 Page:187-197
ISSN:1520-6106
Container-title:The Journal of Physical Chemistry B
language:en
Short-container-title:J. Phys. Chem. B

Author:

Dickinson Edmund J. F.¹,Freitag Leon¹,Compton Richard G.¹

Affiliation:

1. Department of Chemistry, Physical and Theoretical Chemistry Laboratory, Oxford University, South Parks Road, Oxford, United Kingdom OX1 3QZ

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Surfaces, Coatings and Films,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp908024s

Reference31 articles.

1. Ueber die Erregung von Electricität und Wärme in Electrolyten

2. Ueber die Potentialdifferenz zwischen zwei verdünnten Lösungen binärer Electrolyte

3. In the case of a finitely positioned impermeable membrane, however, the liquid junction potential is not constant and an attainable equilibrium of zero concentration gradient exists, where the liquid junction potential is zero (cf. ref14). However, if the membrane is permeable to any species, the diffuse layer outside that membrane must be considered. Finitely positioned Dirichlet conditions are therefore to our minds unphysical for any system, excepting the imposition of a convectional Nernst layer.

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