A New 1,1‘-Binaphthyl-Based Catalyst for the Enantioselective Phenylacetylene Addition to Aromatic Aldehydes without Using a Titanium Complex
Author:
Affiliation:
1. Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904-4319
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol027110q
Reference25 articles.
1. The Discovery of Novel Reactivity in the Development of C−C Bond-Forming Reactions: In Situ Generation of Zinc Acetylides with ZnII/R3N
2. (b) We further found that the BINOL-Ti(OiPr)4catalyst can also catalyze the highly enantioselective phenylacetylene addition to aliphatic and α,β-unsaturated aldehydes: Gao, G.; Moore, D.; Xie, R.G.; Pu, L.Org. Lett.2002, ASAP.
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