Synthetic, Structural, Chemical, and Electrochemical Studies of the Metallatricarbadecaboranyl Analogues of Ferrocene, Ruthenocene, and Osmocene and the Observation of a Reversible η6−η4 Tricarbadecaboranyl Coordination that Is Analogous to the η5−η3 Cyclopentadienyl Ring-Slippage Process
Author:
Affiliation:
1. Departments of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, and University of Vermont, Burlington, Vermont 05405
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om020757u
Reference42 articles.
1. Syntheses and Structural Characterizations of Metallabis(tricarbadecaboranyl) Sandwiches, (η4-MeC3B7H9)2M (M = Ni, Pd, Pt): Tricarbadecaboranyl Analogs of (η3-C3H5)2M Complexes
2. Hybrid Diborolyl/Tricarbadecaboranyl Triple-Deckers: (.eta.5-Cyclopentadienyl)cobalt-(.mu.-.eta.5-1,3-Diborolyl)metal-(.eta.6- and .eta.4-Tricarbadecaboranyl) Complexes (M = Fe, Co, Ni). Triple-Decker Complexes with Open Cage Distortions
3. Syntheses and Structural Characterizations of Ferra- and Cobaltacarborane Complexes Derived from the arachno-6-R-5,6,7-C3B7H12 [R- = NCCH2-, MeOC(O)CH2-, MeC(O)CH2-] Tricarbaborane1
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