New Photorearrangements of 2-Cyclopentenones. The Genesis and Fate of Cyclopropylcarbinyl Biradical Intermediates

Author:

Paquette Leo A.1,Zhao Zhong1,Gallou Fabrice1,Liu Jian1

Affiliation:

1. Evans Chemical Laboratories, The Ohio State University Columbus, Ohio 43210

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference21 articles.

1. The Tricyclo[5.3.0.02,6]decane System. The Photodimers of Cyclopentenone

2. Photodimerization of Cyclopentenone. Singlet or Triplet?1

3. New insights into an old mechanism: [2 + 2] photocycloaddition of enones to alkenes

4. Select reviews:  (a) Crimmins, M. T.Chem. Rev.1988,88, 1453. (b) Crimmins, M. T.; Reinhold, T. L.Org. React. (NY)1993,44, 297. (c) Crimmins, M. T. inComprehensiveOrganic Synthesis, Vol. 5; Trost, B. M., Fleming, I., Paquette, L. A., Eds.; Pergamon:  Oxford, 1991; pp 123−150. (d) Winkler, J. D.; Bowen, C. M.; Liotta, F.Chem. Rev.1995,95, 2003.

5. Determination of the Relative Rates of Formation, Fates, and Structures of Triplet 1,4-Biradicals Generated in the Photochemical Cycloaddition Reactions of 2-Cyclopentenones with 2-Methylpropene

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