Conversion of 2-Alkyl-2-(2-oxopropyl)cyclopentane-1,3-diones into 2,3,5- and 2,3,4-Trisubstituted Cyclopent-2-enones by Intramolecular Aldolizations to 2,3-Diacylcyclopropanolates Followed by Remarkable Skeletal Rearrangements1-Reference-Cited by-同舟云学术

Conversion of 2-Alkyl-2-(2-oxopropyl)cyclopentane-1,3-diones into 2,3,5- and 2,3,4-Trisubstituted Cyclopent-2-enones by Intramolecular Aldolizations to 2,3-Diacylcyclopropanolates Followed by Remarkable Skeletal Rearrangements1

Published:1996-01-01 Issue:17 Volume:61 Page:5788-5792
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Schick Hans¹,Roatsch Birgit¹,Schramm Siegfried¹,Gilsing Hans-Detlev¹,Ramm Matthias¹,Gründemann Egon¹

Affiliation:

1. Institut für Angewandte Chemie Berlin-Adlershof e.V., Rudower Chaussee 5, D-12484 Berlin, Germany, AERES Angewandte Umweltforschung GmbH, Rudower Chaussee 5, D-12484 Berlin, Germany, Martin-Luther-Universität Halle-Wittenberg, Institut für Organische Chemie, Geusaer Strasse, D-06217 Merseburg, Germany, and Freie Universität Berlin, Institut für Kristallographie, D-14195 Berlin, Germany

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo960189q

Reference27 articles.

1. Neuartige asymmetrische Cyclisierung zu optisch aktiven Steroid-CD-Teilstücken

2. Total syntheses of optically active 19-nor steroids. (+)-Estr-4-ene-3,17-dione and (+)-13.beta.-ethylgon-4-ene-3,17-dione

3. The course of cyclic ethylene acetal formation from 7a-methyl-2,3,7,7a-tetrahydro-1 H-indene-l,5(6H)-dione

4. Synthesis of ent-cholesterol, the unnatural enantiomer

5. Experiments in steroid synthesis: oestrone

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