Distinguishing Rate-Limiting Electron versus H-Atom Transfers in Cu2(O2)-Mediated Oxidative N-Dealkylations: Application of Inter- versus Intramolecular Kinetic Isotope Effects-Reference-Cited by-同舟云学术

Distinguishing Rate-Limiting Electron versus H-Atom Transfers in Cu2(O2)-Mediated Oxidative N-Dealkylations: Application of Inter- versus Intramolecular Kinetic Isotope Effects

Published:2003-09-25 Issue:42 Volume:125 Page:12670-12671
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Shearer Jason¹,Zhang Christiana Xin¹,Hatcher Lanying Q.¹,Karlin Kenneth D.¹

Affiliation:

1. Department of Chemistry, Johns Hopkins University, 3400 North Charles Street, Baltimore, Maryland 21218

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0359409

Reference20 articles.

1. Multicopper Oxidases and Oxygenases

2. Bis(μ-oxo)dimetal “Diamond” Cores in Copper and Iron Complexes Relevant to Biocatalysis

3. Oxygen and Hydrogen Isotope Effects in an Active Site Tyrosine to Phenylalanine Mutant of Peptidylglycine α-Hydroxylating Monooxygenase: Mechanistic Implications

4. Investigation of the Reactive Oxygen Intermediate in an Arene Hydroxylation Reaction Performed by Xylyl-Bridged Binuclear Copper Complexes

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