Insertion of Terminal and Internal Acetylenes into the Zr−μ-Methylene Bond of the Dinuclear Cationic Zirconium Complex [{Zr(η5-C5H5)}2(μ-CH2)(μ-Cl)(μ-η5-C5H4-η5-C5H4)][BMe(C6F5)3]. Synthetic Aspects, NMR Spectroscopic Study, and Dynamic Behavior in Solution
Author:
Affiliation:
1. Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, 28871 Alcalá de Henares, Spain
2. NMR Spectroscopy Center, Universidad de Alcalá, Campus Universitario, 28871 Alcalá de Henares, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om000664h
Reference75 articles.
1. A Structurally Distorted Ligand in an Electron-Deficient Dizirconocene Cation: Unusual 1,2- and 1,1-Dimetallioalkenes
2. Monomer–Dimer Equilibria in Homo- and Heterodinuclear Cationic Alkylzirconium Complexes and Their Role in Polymerization Catalysis
3. Cationic Zirconocene Olefin Polymerization Catalysts Based on the Organo-Lewis Acid Tris(pentafluorophenyl)borane. A Synthetic,Structural, Solution Dynamic, and Polymerization Catalytic Study
4. Unexpected reactions of pentafluorophenylboron compounds with η-cyclopentadienyl(benzamidinato)zirconium derivatives
5. Determination of the Stabilization Energy of Planar-Tetracoordinate Carbon in Dynamic Dinuclear (.mu.-Hydrocarbyl)bis(zirconocene) Cation Complexes and Detection of an Organometallic Memory Effect in Their Formation
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