Controlling Regiochemistry in Negishi Carboaluminations. Fine Tuning the Ligand on Zirconium
Author:
Affiliation:
1. Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja065769b
Reference23 articles.
1. Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins
2. Zirconium porphyrins as novel active catalysts for highly regio- and stereo-selective ethylalumination of alkynes
3. Mechanism of the zirconium-catalyzed carboalumination of alkynes. Evidence for direct carboalumination
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