Oxidative Addition of X−H (X = C, N, O) Bonds to [Ir(PMe3)4]Cl and Catalytic Hydration of Acetonitrile Using its Peroxo Derivative, [Ir(O2)(PMe3)4]Cl, as Catalyst Precursor-Reference-Cited by-同舟云学术

Oxidative Addition of X−H (X = C, N, O) Bonds to [Ir(PMe3)4]Cl and Catalytic Hydration of Acetonitrile Using its Peroxo Derivative, [Ir(O2)(PMe3)4]Cl, as Catalyst Precursor

Published:2009-04-14 Issue:9 Volume:28 Page:2904-2914
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Crestani Marco G.¹,Steffen Andreas¹,Kenwright Alan M.¹,Batsanov Andrei S.¹,Howard Judith A. K.¹,Marder Todd B.¹

Affiliation:

1. Facultad de Química, Universidad Nacional Autónoma de México, México, D.F. 04510, Mexico, and Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, U.K.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9000633

Reference80 articles.

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5. The rate of hydrolysis of the amide to the corresponding carboxylic acid is usually greater than that of the precursor nitrile to the amide, therefore making their straightforward synthesis by conventional acid/base conditions difficult. See:

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