Transition Metal Intervention for a Classic Reaction: Assessing the Feasibility of Nickel(0)-Promoted [1,3] Sigmatropic Shifts of Bicyclo[3.2.0]hept-2-enes
Author:
Affiliation:
1. Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California 95616
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om100419j
Reference57 articles.
1. Inversion of configuration in the migrating group of a thermal 1,3-sigmatropic rearrangement
2. Subjacent orbital control. Electronic factor favoring concertedness in Woodward-Hoffmann forbidden reactions
3. Orbital-symmetry-forbidden reactions
4. Steric prohibition of the inversion pathway. Test of the orbital symmetry prediction of the sense of rotation in thermal suprafacial 1,3-sigmatropic rearrangements
5. Thermal Rearrangement of 7-Methylbicyclo[3.2.0]hept-2-ene: An Experimental Probe of the Extent of Orbital Symmetry Control in the [1,3] Sigmatropic Rearrangement
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