Concerted Proton−Electron Transfers: Electrochemical and Related Approaches-Reference-Cited by-同舟云学术

Concerted Proton−Electron Transfers: Electrochemical and Related Approaches

Published:2010-03-16 Issue:7 Volume:43 Page:1019-1029
ISSN:0001-4842
Container-title:Accounts of Chemical Research
language:en
Short-container-title:Acc. Chem. Res.

Author:

Costentin Cyrille¹,Robert Marc¹,Savéant Jean-Michel¹

Affiliation:

1. Laboratoire d’Electrochimie Moléculaire, Unité Mixte de Recherche Université - CNRS No 7591, Université Paris Diderot, Bâtiment Lavoisier, 15 rue Jean de Baïf, 75205 Paris Cedex 13, France

Publisher

American Chemical Society (ACS)

Subject

General Medicine,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ar9002812

Reference30 articles.

1. aThe notion of concerted proton-electron transfer is also recent.(1b)

2. Concerted Electron and Proton Movement in Quenching of Triplet C60 and Tetracene Fluorescence by Hydrogen-Bonded Phenol-Base Pairs

3. cThere is unfortunately no consensus on definitions and acronyms. We use PCET (proton-coupled electron transfer) for all reactions in which, whatever the mechanism, reactant and product systems differ by the exchange of one electron and one proton. CPET is reserved for PCET reactions in which electron and proton transfers are concerted. The most perturbing aspect of this lack of agreement on nomenclature, which should particularly alert the reader, is that some authors use PCET or EPT to mean CPET. Much less serious is the replacement, in the designation of stepwise pathways, of EPT and PET by ETPT and PTET.

4. Electrochemical concerted proton and electron transfers. Potential-dependent rate constant, reorganization factors, proton tunneling and isotope effects

5. Adiabatic and Non-adiabatic Concerted Proton−Electron Transfers. Temperature Effects in the Oxidation of Intramolecularly Hydrogen-Bonded Phenols

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