Deuterium Kinetic Isotope Effects in the Gas-Phase SN2 Reactions of Solvated Fluoride Ions with Methyl Halides
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, Department of Chemistry, Middle East Technical University, 06531 Ankara, Turkey, and Department of Chemistry, University of Idaho, Moscow, Idaho 83844
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp040362j
Reference26 articles.
1. Gas phase nucleophilic substitution
2. Reactions of mass-selected cluster ions in a thermal bath gas
3. Gas-phase solvated negative ions
4. Gas-phase measurements of the influence of stepwise solvation on the kinetics of SN2 reactions of solvated F− with CH3Cl and CH3Br and of solvated Cl− with CH3Br
5. Temperature Dependences of the Rate Constants and Branching Ratios for the Reactions of F-(H2O)0-5 with CH3Br
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