Triple Bonding to Germanium: Characterization of the Transition Metal Germylynes (η5-C5H5)(CO)2M⋮Ge-C6H3-2,6-Mes2 (M = Mo, W; Mes = −C6H2-2,4,6-Me3) and (η5-C5H5)(CO)2M⋮Ge-C6H3-2,6-Trip2 (M = Cr, Mo, W; Trip = −C6H2-2,4,6-i-Pr3) and the Related Single Bonded Metallogermylenes (η5-C5H5)(CO)3M-G̈e-C6H3-2,6-Trip2 (M = Cr, W)
Author:
Affiliation:
1. Contribution from the Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California 95616
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja992937%2B
Reference34 articles.
1. Synthesis and Characterization of the Monomeric Diaryls M{C6H3-2,6-Mes2}2 (M = Ge, Sn, or Pb; Mes = 2,4,6-Me3C6H2−) and Dimeric Aryl−Metal Chlorides [M(Cl){C6H3-2,6-Mes2}]2 (M = Ge or Sn)
2. Phosphorus- and Arsenic-Bridged Complexes of Metal Carbonyls. II. Cyclopentadienylnickel, molybdenum, and tungsten Complexes
3. (η5-C5H5)(CO)2MoGeC6H3-2,6-Mes2: A Transition-Metal Germylyne Complex
4. Transition metal complexes containing donor-stabilized silylyne ligands. Reductive dimerization to a silylene complex
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