Electrochemical and IR/UV−Vis Spectroelectrochemical Studies of fac-[Mn(X)(CO)3(iPr-DAB)]n (n = 0, X = Br, Me, Bz; n = +1, X = THF, MeCN, nPrCN, P(OMe)3; iPr-DAB = 1,4-Diisopropyl-1,4-diaza-1,3-butadiene) at Variable Temperatures: Relation between Electrochemical and Photochemical Generation of [Mn(CO)3(α-diimine)]--Reference-Cited by-同舟云学术

Electrochemical and IR/UV−Vis Spectroelectrochemical Studies of fac-[Mn(X)(CO)3(iPr-DAB)]n (n = 0, X = Br, Me, Bz; n = +1, X = THF, MeCN, nPrCN, P(OMe)3; iPr-DAB = 1,4-Diisopropyl-1,4-diaza-1,3-butadiene) at Variable Temperatures: Relation between Electrochemical and Photochemical Generation of [Mn(CO)3(α-diimine)]-

Published:1997-10-01 Issue:21 Volume:16 Page:4675-4685
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Rossenaar Brenda D.¹,Hartl František¹,Stufkens Derk J.¹,Amatore Christian¹,Maisonhaute Emmanuel¹,Verpeaux Jean-Noël¹

Affiliation:

1. Anorganisch Chemisch Laboratorium, J. H. van't Hoff Research Instituut, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands, and Ecole Normale Supérieure, Département de Chimie, URA CNRS 1679, 24 rue Lhomond, 75231 Paris Cedex 05, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9702791

Reference51 articles.

1. Metal to ligand charge transfer photochemistry of Re(I)-alkyl complexes

2. Spectroelectrochemical (IR, UV/Vis) Determination of the Reduction Pathways for a Series of [Re(CO)3(.alpha.-diimine)L']0/+ (L' = Halide, OTf-, THF, MeCN, n-PrCN, PPh3, P(OMe)3) Complexes

3. The Remarkable Photochemistry of fac-XMn(CO)3(.alpha.-diimine) (X =Halide): Formation of Mn2(CO)6(.alpha.-diimine)2 via the mer Isomer and Photocatalytic Substitution of X- in the Presence of PR3

4. Metal-to-Ligand Charge Transfer (MLCT) Photochemistry of fac-Mn(Cl)(CO)3(H-DAB): A Density Functional Study

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