[(tBu2PCH2SiMe2)2N]RuCH3: The Origin of Extremely Facile, Double H−C(sp3) Activation Generating a “Hydrido-Carbene” Complex
Author:
Affiliation:
1. Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, Indiana
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja052973a
Reference19 articles.
1. Four-Coordinate, Planar Ru(II). A Triplet State as a Response to a 14-Valence Electron Configuration
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4. Triple C–H activation of 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane on ruthenium gives a chiral carbene complex
5. Trimethylphosphine as a reactive solvent: synthesis, crystal structures, and reactions of [Ta(PMe3)3(η2-CH2PMe2)(η2-CHPMe2)] and [W(PMe3)4(η2-CH2PMe2)H] and related studies
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1. Bis(pentalene)dititanium chemistry: C–H, C–X and H–H bond activation;Dalton Transactions;2018
2. Isolation of [Ru(IPr)2(CO)H]+ (IPr = 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene) and Reactivity toward E–H (E = H, B) Bonds;Organometallics;2016-04-26
3. Synthesis and reactivity of dinuclear Cp*Ru tert-butylamido and cyclometallated Bis(trimethylsilyl)amido complexes;Journal of Organometallic Chemistry;2015-11
4. Implication of a σ-Methane Complex en Route to Elimination of Methane from a Ruthenium Complex: An Experimental and Theoretical Investigation;Organometallics;2015-03-24
5. Bond Activation and Catalysis by Ruthenium Pincer Complexes;Chemical Reviews;2014-11-14
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