Double Activation of the Geminal Carbon−Hydrogen Bonds in 1,3-Butadiene by a Diiridium Complex
Author:
Affiliation:
1. Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada T6G 2G2
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0006054
Reference39 articles.
1. Carbon-hydrogen insertion and .pi.-complex formation reactions of (.eta.5-C5Me5)(PMe3)Ir with ethylene: an intra- and intermolecular isotope effect study
2. Insertion of iridium into the carbon-hydrogen bonds of alkenes: the .pi.-complex cannot be an intermediate
3. A New Alkene Carbon-Hydrogen Bond Activation Reaction: Facile and Stereospecific Vinylic Deprotonation of the Chiral Cationic Rhenium Alkene Complexes [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+BF4-
4. Competition between intramolecular and intermolecular carbon-hydrogen bond activation in iridium ethene complexes
5. Thermal and photochemical carbon-hydrogen bond activation reactions at iridium. .pi.-Coordination vs. C-H cleavage of ethene, styrene, and phenylacetylene
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