Stereoelectronic Influence of the Type of Bifunctional ansa-Monocyclopentadienyldimethylsilylamido Ligand on the Molecular Structures Displayed by Zirconium Dichloride and 1,4-Diphenylbutadiene Complexes
Author:
Affiliation:
1. C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, West Virginia 26505-6045
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic040001i
Reference50 articles.
1. Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in Solution
2. Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalyst
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