Reactions of [Ru(CO)2(PPh3)3] with Alkynylphosphonium Salts: Phosphaallenylidene vs Phosphonioacetylide Coordination-Reference-Cited by-同舟云学术

Reactions of [Ru(CO)2(PPh3)3] with Alkynylphosphonium Salts: Phosphaallenylidene vs Phosphonioacetylide Coordination

Published:2009-07-30 Issue:16 Volume:28 Page:4880-4885
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Cordiner Richard L.¹,Hill Anthony F.¹,Wagler Jörg¹²

Affiliation:

1. Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, Australian Capital Territory, Australia

2. Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Freiberg, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9003384

Reference57 articles.

1. Triphenylphosphonioacetylide: A Species Isoelectronic with Isocyanides

2. A simple high-yield preparation of alkynylphosphonium triflates

3. Notes- Aryl-and Arylalkyl-Isocyanosilanes

4. Trialkyl- and Triaryl(iso)cyanosilanes1

5. cWe find that calculations at the same level of theory (B3LYP, 6-311G*) used to investigate the bonding in Ph3PCC1suggest that cyanotriphenylsilane is ca.13.6 kJ mol−1more stable than isocyanotriphenylsilane, i.e., for3→iso-3,K300 K≈ 6 × 10−3. (assuming ΔG≈ ΔH). Nevertheless, in the presence of transition metals, cyanosilanes have been found on occasion to rearrange to complexes of isocyanosilanes:

Cited by 10 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Zerovalent ruthenium complexes of secondary alkoxyphosphines;Journal of Organometallic Chemistry;2024-04

2. Hydrogenating an organometallic carbon chain: buten-yn-diyl (CHCHCC) as a missing link;Dalton Transactions;2019

3. Organometallic chemistry of ethynyl boronic acid MIDA ester, HCCB(O2CCH2)2NMe;Dalton Transactions;2015

4. η2-Allenyl- and η2-Alkynylphosphonium Complexes of Platinum;Organometallics;2013-08-21

5. Phosphonium salts and P-ylides;Organophosphorus Chemistry;2011-04-27