Thermodynamic Analysis of the Main Reactions Involved in the Synthesis of Organosilanes

Author:

Xia Zhenkun12,Gao Jiajian3ORCID,Sun Xiaomeng4,Wang Kangjun1,Xu Guangwen15ORCID,Zhong Ziyi67ORCID,Su Fabing25ORCID

Affiliation:

1. Key Laboratory on Resources Chemicals and Materials (Shenyang University of Chemical Technology), Ministry of Education, Shenyang 110142, China

2. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

3. Institute of Sustainability for Chemicals, Energy and Environment (ISCE2), Agency for Science, Technology, and Research (A*STAR), 1 Pesek Road, Jurong Island, Singapore 627833, Singapore

4. Exploration and Development Research Institute, PetroChina Southwest Oil & Gasfield Company, Chengdu 610041, China

5. Institute of Industrial Chemistry and Energy Technology, Shenyang University of Chemical Technology, Shenyang 110142, China

6. Department of Chemical Engineering, Guangdong Technion-Israel Institute of Technology (GTIIT), 241 Daxue Road, Shantou 515063, China

7. Technion-Israel Institute of Technology (IIT), Haifa 32000, Israel

Funder

General Research Institute for Nonferrous Metals

State Key Laboratory of Multi-phase Complex Systems, Chinese Academy of Sciences

Guangdong Province Key discipline fund

Publisher

American Chemical Society (ACS)

Reference52 articles.

1. Carbofunctional sulfur-containing organosilicon compounds: Synthesis and application fields

2. The “direct” synthesis of trialkoxysilanes: New data for understanding the processes of the copper-containing active sites formation during the activation of the initial silicon based contact mass

3. Direct reaction between silicon and methanol over Cu-based catalysts: investigation of active species and regeneration of CuCl catalyst

4. Yang, S.; Yuan, F.; Huang, G.; Ding, Y.; Liu, C.; Organoacetoxysilane preparation comprises reacting organochlorosilane and acetic acid to obtain organoacetoxysilane solution, recycling organic solution of organoacetoxysilane solution, and removing low-boiling component; CN101323625-A; CN101323625-B.

5. Sun, Y.; Xia, Y.; Zhao, Z.; Manufacture of hexamethyldisilazane involves reacting trimethylchlorosilane and reaction solvent, introducing ammonia gas, reacting, washing reaction product, separating hexamethyldisilazane crude product and rectifying; CN102766155-A; CN102766155-B.

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