Diastereofacial Selectivity in Reactions of 5-Substituted (X) Adamant-2-yl Cations: Manifestations of Electron Demand
Author:
Affiliation:
1. Department of Chemistry, The Flinders University of South Australia, Adelaide, Australia 5001
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo970600p
Reference37 articles.
1. Geometric equivalents of enantiomers in studies of the stereochemical course of substitution at carbon. Electronic effects in nucleophilic addition to carbonyl groups and to carbocations. Virtual proof of the existence of .sigma. participation by unstrained carbon-carbon bonds
2. Face Selection in Additions to the Trigonal C2 Site in Quaternized 5-Azaadamantane Derivatives
3. Reduction of Adamantanone: Face Selection Induced by 4-Halo and 4,9-Dihalo Substitution
4. Transmission of polar substituent effects in the adamantane ring system as monitored by 19F NMR: hyperconjugation as a stereoinductive factor
5. Electrostatic vs Hyperconjugative Effects as Stereoinductive Factors in the Adamantane Ring System
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1. Intra- and Intermolecular Reaction Selectivities of γ-Substituted Adamantanylidenes;The Journal of Organic Chemistry;2012-01-12
2. ChemInform Abstract: Diastereofacial Selectivity in Reactions of 5-Substituted (X) Adamant-2-yl Cations: Manifestations of Electron Demand.;ChemInform;2010-06-24
3. Gas-Phase Facial Diastereoselectivity of Equatorial and Axial 4-Chloro-adamant-2-yl Cations;The Journal of Organic Chemistry;2009-06-18
4. Gas-Phase Diastereoselectivity of Secondary 5-Substituted (X)-Adamant-2-yl (X = F, Si(CH3)3) Cations;The Journal of Organic Chemistry;2007-04-28
5. A Rhenium–Cyclohexane Complex with Preferential Binding of Axial CH Bonds: A Probe into the Relative Ability of CH, CD, and CC Bonds as Hyperconjugative Electron Donors?;Angewandte Chemie International Edition;2006-07-03
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