An Investigation into the Identities and the Relative Concentrations of the Zr−Polymeryl Species Present during Ethylene and Propylene Polymerizations by Zirconocene-Based Ziegler Catalysts-Reference-Cited by-同舟云学术

An Investigation into the Identities and the Relative Concentrations of the Zr−Polymeryl Species Present during Ethylene and Propylene Polymerizations by Zirconocene-Based Ziegler Catalysts

Published:2005-10-25 Issue:24 Volume:38 Page:9944-9949
ISSN:0024-9297
Container-title:Macromolecules
language:en
Short-container-title:Macromolecules

Author:

Vatamanu Mihaela¹,Boden Britta N.¹,Baird Michael C.¹

Affiliation:

1. Department of Chemistry, Queen's University, Kingston, ON K7L 3N6, Canada

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ma051947u

Reference70 articles.

1. Homogeneous group 4 metallocene ziegler-natta catalysts: The influence of cyclopentadienyl-ring substituents

2. Evidence of Zircononium−Polymeryl Ion Pairs from 13C NMR in Situ 13C2H4 Polymerization with Cp2Zr(13CH3)2-Based Catalysts

3. Catalytic Propene Polymerization: Determination of Propagation, Termination, and Epimerization Kinetics by Direct NMR Observation of the (EBI)Zr(MeB(C6F5)3)propenyl Catalyst Species

4. Direct Observation of Insertion Events at rac-(C2H4(1-indenyl)2)Zr(MeB(C6F5)3)−Polymeryl Intermediates: Distinction between Continuous and Intermittent Propagation Modes

5. Reactivity of Secondary Metallocene Alkyls and the Question of Dormant Sites in Catalytic Alkene Polymerization

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