Insertion Reactions of (PPh3)2Pt(SR)2 with CS2, where R = H, CMe3, CHMe2, 4-C6H4Me; Structure of (PPh3)Pt(SC6H4Me)(S2CS-4-C6H4Me)
Author:
Affiliation:
1. Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec, Canada, H3A 2K6
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic000825%2B
Reference10 articles.
1. Homogeneous Catalysts for Claus Chemistry: The Preparation and Structure ofcis-[(PPh3)2PtS3O], a Catalytically Active Intermediate
2. (a) Bennett, M. A.; Bruce, M. I.; Matheson, T. W.ComprehensiveOrganometallic Chemistry; Wilkinson, G., ed.; Pergamon Press: Toronto, 1982; Vol. 4, p 778. b) Kubas, G. J.; Ryan, R. R.Polyhedron1986,5, 473. c) Schenk, W. A.Angew.Chem.Int. Ed. Engl.1987,26, 98. d) Kubas, G. J.Inorg. Chem.1979,18, 182. e) Wojcicki, A.Adv. Organomet. Chem.1974,12, 31. f) Jacobson, S. E.; Wojcicki, A.J. Am. Chem. Soc.1973,95, 6921.
3. Alkoxo and hydroxo complexes of platinum(II). Novel insertion reactions into platinumoxygen bonds and condensations with compound containing active hydrogen atoms
4. Preparation of (.eta.-C5H5)Ru(PPh3)(L)SR (R = 1-C3H7, CHMe2, 4-C6H4Me; L = PPh3, CO) and insertion of CS2 into the Ru-SR bond to give the thioxanthates (.eta.-C5H5)Ru(PPh3)S2CSR (R = 1-C3H7, CHMe2, 4-C6H4Me). Crystal structure of (.eta.-C5H5)Ru(PPh3)S2CS-1-C3H7
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