Low Coordinate, Monomeric Molybdenum and Tungsten(III) Complexes: Structure, Reactivity and Calculational Studies of (silox)3Mo and (silox)3ML (M = Mo, W; L = PMe3, CO; silox = tBu3SiO)-Reference-Cited by-同舟云学术

Low Coordinate, Monomeric Molybdenum and Tungsten(III) Complexes: Structure, Reactivity and Calculational Studies of (silox)3Mo and (silox)3ML (M = Mo, W; L = PMe3, CO; silox = tBu3SiO)

Published:2008-09-06 Issue:39 Volume:130 Page:12931-12943
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Kuiper David S.¹,Wolczanski Peter T.¹,Lobkovsky Emil B.¹,Cundari Thomas R.¹

Affiliation:

1. Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, and Department of Chemistry, Center for Advanced Scientific Computing and Modeling (CASCaM), P.O. Box 305070, University of North Texas, Denton, Texas 76203

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja802706u

Reference77 articles.

1. Symmetry and Geometry Considerations of Atom Transfer: Deoxygenation of (silox)3WNO and R3PO (R = Me, Ph, tBu) by (silox)3M (M = V, NbL (L = PMe3, 4-Picoline), Ta; silox = tBu3SiO)

2. Olefin Substitution in (silox)3M(olefin) (silox = tBu3SiO; M = Nb, Ta): The Role of Density of States in Second vs Third Row Transition Metal Reactivity

3. Molybdenum and Tungsten Structural Differences are Dependent on ndz2/(n + 1)s Mixing: Comparisons of (silox)3MX/R (M = Mo, W; silox = tBu3SiO)

4. Valence Bond Concepts Applied to the Molecular Mechanics Description of Molecular Shapes. 4. Transition Metals with π-Bonds

5. Valence Bond Concepts Applied to the Molecular Mechanics Description of Molecular Shapes. 3. Applications to Transition Metal Alkyls and Hydrides

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