Rhodium-Mediated Intramolecular C−H Insertion:  Probing the Geometry of the Transition State

Author:

Taber Douglass F.1,Malcolm Scott C.1

Affiliation:

1. Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference18 articles.

1. For general reviews of rhodium-mediated C−H insertions, see:  (a) Taber D. F.Comprehensive Organic Synthesis; Pattenden, G., Ed.; Pergamon Press:  Oxford, 1991; Vol. 3, pp 1045−1062. (b) Doyle, M. P. InHomogeneous Transition Metal Catalysts in Organic Synthesis; Moser, W. R., Slocum, D. W., Eds.; ACS Advanced Chemistry Series, No. 230; American Chemical Society:  Washington, D.C., 1992; Chapter 30. (c) Padwa, A.; Austin, D. J.Angew. Chem., Int. Ed. Engl.1994,33, 1797−1815. (d) Ye, T.; McKervey, M. A.Chem. Rev.1994,94, 1091−1160.

2. A general approach to the synthesis of C8-oxygenated guaianolides

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