1. Structural and Functional Aspects of Metal Sites in Biology
2. Transition Metal Sulfur Chemistry
3. N-Heterocyclic Carbene Stabilized trans-Dihydrido Aqua and Ethanol Complexes of Ruthenium: Precursors to Complexes with Ru−Heteroatom Bonds
4. 1H NMR (300 MHz, C6D6, 298 K): δ 6.80 (br s, 4H, C6H2Me3), 6.77 (br s, 4H, C6H2Me3), 6.20 (s, 4H, CNCHCHN), 2.32 (s, 12H, CH3), 2.16 (s, 12H, CH3), 2.08 (s, 12H, CH3), −0.58 (s, 2H, SH2), −24.47 (s, 2H, RuH).13C{1H}: δ 202.6 (s, Ru−CO), 197.3 (s, Ru−C), 137.6 (s, N−C), 136.8 (s,C−p-CH3), 136.0 (s,C−o-CH3), 135.7 (s,C−o-CH3), 129.1 (s,m-CH), 121.8 (s, NCHCHN), 21.2 (s,p-CH3), 19.3 (s,o-CH3), 19.2 (s,o-CH3). IR (Nujol): 1879 cm-1(νCO).