Synthesis of N,C Bound Sulfur, Selenium, and Tellurium Heterocycles via the Reaction of Chalcogen Halides with −CH3 Substituted Diazabutadiene Ligands
Author:
Affiliation:
1. Department of Chemistry, The University of Western Ontario, 1151 Richmond St., London, Ontario, N6A 5B7, Canada
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic802320s
Reference25 articles.
1. Redox Reactions between Phosphines (R3P; R = nBu, Ph) or Carbene (iPr2IM) and Chalcogen Tetrahalides ChX4 (iPr2IM = 2,5-diisopropylimidazole-2-ylidene; Ch = Se, Te; X = Cl, Br)
2. Synthesis and characterization of cationic selenium–nitrogen heterocycles from tert-butyl-DAB (DAB = 1,4-di-tert-butyl-1,3-diazabutadiene) and SeX4via the reductive elimination of X2 (X = Cl, Br): a distinct contrast with tellurium
3. Selenium Heterocycles: Reactions of SeX 4 (X = Cl, Br) with the Enamine Form of β‐Diketiminato Ligands
4. The direct reaction of the tBu-DAB ligand with SeCl4: a redox route to selenium–nitrogen heterocycles
5. Heavy Atom Analogues of 1,2,3-Dithiazolylium Salts: Preparation, Structures and Redox Chemistry
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