Synthesis and Characterization of the Dinuclear Polyhydrides [Os2H7(PPhiPr2)4]+ and [Os2H6(PPhiPr2)4]
Author:
Affiliation:
1. School of Chemical and Physical Sciences, Victoria University of Wellington, Wellington, New Zealand
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic900111s
Reference46 articles.
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2. Transition-metal polyhydride complexes
3. Dinuclear polyhydrides of rhenium: isolation and characterization of diamagnetic and paramagnetic complexes containing the octahydrodirhenium(n+) ([Re2H8]n+), heptahydrodirhenium((n + 1)+) ([Re2H7](n+1)+), and pentahydrodirhenium((n + 1)+) ([Re2H5](n+1)+) cores (n = 0 or 1) stabilized by phosphine, nitrile, and isocyanide ligands
4. Di- and Trinuclear Polyhydride Complexes Containing Ruthenium and Rhenium. Synthesis, Site Exchange, and H/D Exchange of Hydride Ligands
5. Activation of Organic Substrates on Multi-Metallic Sites of Transition Metal Polyhydride Clusters Having C5Me5 Groups as Auxiliary Ligands
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