Formation and Dynamic Properties of the Triangular Rhodium μ3-Sulfido Complex [Rh3Cp*3(μ3-η2-||-C2H2)(μ3-S)]2+ (Cp* = η5-C5Me5), Including an Acetylene Ligand Generated by the Coupling and Deprotonation of Two Bridging Methylene Units in a Dirhodium Complex
Author:
Affiliation:
1. Department of Material Science, Himeji Institute of Technology, Harima Science Park City, Hyogo 678-12, Japan
2. Departamento de Química Inorgánica, Universidad de Alcalá de Henares, 28871 Alcalá de Henares, Madrid, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om970796j
Reference24 articles.
1. The lively chemistry of the di-μ-methylene-bis(pentamethylcyclopentadienyl-rhodium) complexes, analogues of surface reactions in heterogeneous catalysis
2. Heterogeneous catalysis of C–C bond formation: black art or organometallic science?
3. Deoxygenative Reduction of Diruthenium Carbonyl Complexes (η5-C5H4R)2Ru2(μ-CO)2(CO)2 with Hydrosilanes Leading to Bridging Methylene Complexes (η5-C5H4R)2Ru2(μ-CH2)n(μ-CO)2-n(CO)2 (n = 1, 2; R = H, CH3)
4. Deoxygenative Reduction of Diruthenium Carbonyl Complexes (η5-C5H4R)2Ru2(μ-CO)2(CO)2 with Hydrosilanes Leading to Bridging Methylene Complexes (η5-C5H4R)2Ru2(μ-CH2)n(μ-CO)2-n(CO)2 (n = 1, 2; R = H, CH3)
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