Unexpected Metallosite-Selective CO Substitution of Heteronuclear Tetrahedral (μ3-S)FeCoM (M = Mo, W) Carbonyl Clusters with Cyclohexyl Isocyanide: 59Co NMR and 57Fe Mössbauer Spectra of (μ3-S)FeCoMo(CO)8-n(η5-C5H4COMe)(C6H11NC)n (n = 1−3) and Crystal Structures of (μ3-S)FeCoM(CO)8-n(η5-C5H4R)(C6H11NC)n (M = Mo, W; R = MeCO, MeO2C; n = 1, 2)-Reference-Cited by-同舟云学术

Unexpected Metallosite-Selective CO Substitution of Heteronuclear Tetrahedral (μ3-S)FeCoM (M = Mo, W) Carbonyl Clusters with Cyclohexyl Isocyanide: 59Co NMR and 57Fe Mössbauer Spectra of (μ3-S)FeCoMo(CO)8-n(η5-C5H4COMe)(C6H11NC)n (n = 1−3) and Crystal Structures of (μ3-S)FeCoM(CO)8-n(η5-C5H4R)(C6H11NC)n (M = Mo, W; R = MeCO, MeO2C; n = 1, 2)

Published:2001-10-01 Issue:22 Volume:20 Page:4510-4516
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Song Li-Cheng¹,Luo Chun-Cheng¹,Hu Qing-Mei¹,Chen Jiabi¹,Wang Hong-Gen¹

Affiliation:

1. Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China, State Key Laboratory of Structural Chemistry, Fuzhou, 350002, China, and State Key Laboratory of Organometallic Chemistry, Shanghai 200032, China

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om0104262

Reference28 articles.

1. Metallosite Selectivity Studies in Reactions of Tetrahedral MCo3 Carbonyl Clusters (M = Fe, Ru) with Cyclohexylphosphine. Skeletal Rearrangements Leading to Tri- and Pentanuclear Phosphinidene Clusters and Crystal Structures of RuCo4(μ4-PCy)(μ-CO)2(CO)11 and RuCo2(μ3-PCy)(CO)9

2. Cobalt-59 NMR study of cluster reactions: solvent and ligand effects in mixed-metal, tetrahedral MCo3 (M = iron, ruthenium) carbonyl clusters. Crystal structure of FeCo3(.mu.3-H)(.mu.-CO)3(CO)8(PPh2H)

3. Selectivity in substitution chemistry of mixed-metal, tetrahedral MCo3 (M = iron, ruthenium) carbonyl clusters: cobalt-59 NMR study and crystal structure of RuCo3(.mu.3-H)(.mu.-CO)3(CO)8(NMe3)

4. Site-Selective Substitution Reactions and Isomerizations in Tetrahedral MCo3 Carbonyl Clusters (M = Fe, Ru) with N, P, S, and Te Donor Ligands. Crystal Structures of HRuCo3(CO)10(PMe2Ph)2 and HRuCo3(CO)9(PMe2Ph)3

5. Telluride-substituted mixed metal clusters. Crystal structures of [HRuCo3(CO)11(TeMe2)], [HRuCo3(CO)10(TeMe2)2], and [HRuCo3(CO)11(TePh2)]

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