Reactions of Benzocyclic β-Keto Esters with Tosyl and 4-Nitrophenyl Azide. Structural Influence of Dicarbonyl Substrate and Azide Reagent on Distribution of Diazo, Azide and Ring-Contraction Products
Author:
Affiliation:
1. Dipartimento di Chimica Organica “A. Mangini”, Università di Bologna, Viale Risorgimento 4, I-40136 Bologna, Italy, and Dipartimento di Chimica Generale ed Inorganica, Analitica e Chimica Fisica, Viale delle Scienze 78, I-43100 Parma, Italy
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo980223w
Reference17 articles.
1. Organic Synthesis with .alpha.-Diazo Carbonyl Compounds
2. Synthesis and reactivity of 4-acyl-5-hydroxytriazolines resulting from thermal reaction of aryl and tosyl azides with 2-substituted indane-1,3-diones
3. o-N-tosylcarbamoyl-substituted α-diazoacetophenones: their preparation and decomposition
4. Reactions of tosyl azide with 2-phenoxy- and 2-phenylsulfanyl-2,3-dihydro-1H-indane-1,3-dione. Unexpected reactivity of intermediate 4-acyl-5-hydroxy-1-tosyltriazolines
5. Diazo transfer reactions of tosyl azide with carbocyclic β-keto esters: production and decomposition of ring-opened N-tosylcarbamoyl-substituted α-diazo esters
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