Estimating the Effective Steric Impact of PtBu2Me, PiPr3, and PCy3
Author:
Affiliation:
1. Departments of Chemistry, Indiana University, Bloomington, Indiana 47405-4001, and University of New Orleans, New Orleans, Louisiana 70148
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om960380q
Reference17 articles.
1. Molecular hydrogen complexes of the transition metals. 2. Preparation, structure, and reactivity of W(CO)3(PCy3)2 and W(CO)3(P-iso-Pr3)2, .eta.2-H2 complex precursors exhibiting metal.cntdot..cntdot..cntdot.hydrogen-carbon interaction
2. Syntheses and activities of new single-component, ruthenium-based olefin metathesis catalysts
3. Reactivity of OsH4(CO)(PiPr3)2 toward terminal alkynes: synthesis and reactions of the alkynyl-dihydrogen complexes OsH(C2R)(.eta.2-H2)(CO)(PiPr3)2 (R = Ph, SiMe3)
4. Hydrogenation of benzylideneacetone catalyzed by OsHCl(CO)(PR3)2 (PR3 = P-iso-Pr3, PMe-tert-Bu2): new roles of dihydrogen complexes in homogeneous catalytic hydrogenation
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