Possible Reason for the Unusual Regioselectivity in Nucleophilic Ring Opening of Trisubstituted Aziridines under Mildly Basic Conditions
Author:
Affiliation:
1. Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo5006685
Reference68 articles.
1. Preferred Conformations of Peptides Containingtert-Leucine, a Sterically Demanding, Lipophilic ?-Amino Acid with a Quaternary Side-Chain C? Atom
2. A Regio- and Stereoselective Approach to Quaternary Centers from Chiral Trisubstituted Aziridines
3. Ring Opening of a Trisubstituted Aziridine With Amines: Regio- and Stereoselective Formation of Substituted 1,2-Diamines
4. A Convergent Total Synthesis of Ustiloxin D via an Unprecedented Copper-Catalyzed Ethynyl Aziridine Ring-Opening by Phenol Derivatives
5. Total synthesis and biological evaluation of ustiloxin natural products and two analogs
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