Preparation and Properties of a Closo Nitride Cluster, the Cubane [(η-C5Me5)V(μ3-N)]4
Author:
Affiliation:
1. Departments of Chemistry, University of New Brunswick, Fredericton, New Brunswick, Canada E3B 5A3, and Dalhousie University, Halifax, Nova Scotia, Canada B3H 4J3
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om950947n
Reference15 articles.
1. Organometallic pnicogen complexes. V. Preparation, structure, and bonding of the tetrameric antimony-cobalt cluster system, Co4(CO)12Sb4: the first known (main group element)(metal carbonyl) cubane-type structure
2. Organometallic pnicogen complexes. VII. Synthesis, structure and bonding of the cubane-like metal cluster tetra-.mu.3-phosphido-tetra-.pi.-pentahaptocyclopentadienyl tetracobalt(III) [Co4(h5-C5H5)4P4]. First reported organometallic complex containing a naked phosphorus atom as a ligand
3. Synthesis, stereochemical analysis, and ligand-transformation reactions of new classes of bicapped tricobalt clusters, [Co3(.eta.5-C5H5-xMex)3(.mu.3-X)(.mu.3-Y)]n (x = 0, 1, 5), containing mixed .pi.-acceptor X and .pi.-donor Y capping ligands (X = CO, NO; Y = NSiMe3, NC(O)NH2, NH): a rational preparative route to nitrene (.mu.3-NH) clusters and the unprecedented direct exchange of an isoelectronic .mu.-NO+ ligand for a .mu.-CO ligand
4. Synthese und Struktur von [{η-C5Me5)Ti(NH)}3N], einem Titanimidnitrid
5. Synthesis and molecular structure of the first organometallic nitride cubane: [{Ti(η5-C5Me5)}4(µ3-N)4]
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