Enhanced Reactivity of RC≡CZ− (R = H and Cl; Z = O, S, and Se) and the Influence of Leaving Group on the α-Effect in the E2 Reactions-Reference-Cited by-同舟云学术

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Enhanced Reactivity of RC≡CZ− (R = H and Cl; Z = O, S, and Se) and the Influence of Leaving Group on the α-Effect in the E2 Reactions

Published:2010-05-19 Issue:12 Volume:75 Page:4212-4217
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Wei Xi-Guang¹,Sun Xiao-Ming¹,Wu Xiao-Peng¹,Ren Yi¹²,Wong Ning-Bew²,Li Wai-Kee³

Affiliation:

1. College of Chemistry, and Key State Laboratory of Biotherapy, Sichuan University, Chengdu 610064, China

2. Department of Biology and Chemistry, City University of Hong Kong, Kowloon, Hong Kong

3. Department of Chemistry, The Chinese University of Hong Kong, Shatin, N.T., Hong Kong

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo1006575

Reference62 articles.

1. Reactivity of Nucleophilic Reagents toward Esters

2. The Factors Determining Nucleophilic Reactivities

3. The Influence of solvent and crown polyethers on the nucleophilic reactivity of potassiumtert-Butylperoxide, potassiumtert-Butoxide, and some other oxygen bases

4. The α-effect and its modulation by solvent

5. Efficient Intramolecular General-Acid Catalysis of the Reactions of α-Effect Nucleophiles and Ammonia Oxide with a Phosphate Triester

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1. Benchmark ab initio characterization of the complex potential energy surfaces of the HOO⁻ + CH₃Y [Y = F, Cl, Br, I] reactions;Physical Chemistry Chemical Physics;2024

2. Solvent-induced dual nucleophiles and the α-effect in the S_N2 versus E2 competition;Physical Chemistry Chemical Physics;2024

3. Li₂[SeC₂Se]·2NH₃: A Crystalline Ammoniate with a ^–Se–C≡C–Se^– Dianion;Inorganic Chemistry;2022-11-10

4. Effect of medium on reactivity for alkaline hydrolysis of p-nitrophenyl acetate and S-p-nitrophenyl thioacetate in DMSO–H2O mixtures of varying compositions: ground state and transition state contributions;Canadian Journal of Chemistry;2021-01-24

5. NaSeC 2 H: A Crystalline Compound with Disordered – SeC 2 H Anions;Zeitschrift für anorganische und allgemeine Chemie;2020-05-05

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