Synthesis, Reactions, and Molecular and Electronic Structure of the Radical Cation [Mo2(μ-C8Me8)(η-C5H5)2]+: An Intermediate in the Redox Activation of an Alkyl C−H Bond-Reference-Cited by-同舟云学术

Synthesis, Reactions, and Molecular and Electronic Structure of the Radical Cation [Mo2(μ-C8Me8)(η-C5H5)2]+: An Intermediate in the Redox Activation of an Alkyl C−H Bond

Published:1996-01-23 Issue:2 Volume:15 Page:729-735
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Connelly Neil G.¹,Metz Bernhard¹,Orpen A. Guy¹,Rieger Philip H.¹

Affiliation:

1. School of Chemistry, University of Bristol, Bristol BS8 1TS, U.K., and Department of Chemistry, Brown University, Providence, Rhode Island 02912

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om950529i

Reference20 articles.

1. Electron-transfer mechanism for a hydride-transfer reaction: evidence for selective .alpha.-hydride abstraction from a transition metal alkyl

2. New mechanistic probes of hydride abstraction from rhenium-alkyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(R) by Ph3C+ PF6-. Evidence for initial electron transfer

3. Reactions of (CO)2(η5-C5H5)Fe Alkyls and Ph3C+ BF4

4. Activation of µ-alkylidene ligands through oxidation–deprotonation: a new synthesis of µ-methyne, and is hydrogenation to µ-methyl

5. Activation of a µ3-ethylidyne ligand through oxidation–deprotonation: X-ray structure of [Ru3(µ3-CMe)(µ-CO)3(η-C5Me5)3][BF4]

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5. Structural consequences of the one-electron reduction of d4[Mo(CO)2(η-PhCCPh)Tp′]+and the electronic structure of the d5radicals [M(CO)L(η-MeCCMe)Tp′] {L = CO and P(OCH2)3CEt};Dalton Trans.;2006